New Study Measures Titanium in Apollo Rock to Uncover Moon’s Early Chemistry

The Earth and the Moon may look very different today, but they formed in space. In fact, says that the early Earth was hit by a Mars-sized object, and it was this giant impact that spun off material to form the Moon. But unlike Earth, the Moon lacks and capable of reshaping its surface and over billions of years.

As a result, the Moon preserves a record of the geological conditions that helped shape it and can give scientists insight into the world we live in today. Rocks that were formed during early volcanic activity on the Moon offer a window into events that occurred nearly 4 billion years ago. By uncovering the conditions under which the Moon’s rocks formed, scientists move closer to understanding the origins of our own planet.

published March 2026 in the journal Nature Communications, investigated , a mineral composed of iron, titanium and oxygen, crystallized from an ancient lunar magma. We used to probe the chemical signature of titanium in this ilmenite, finding that about 15% of the titanium carries less of an electrical charge than expected.

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This illustration shows the rock on the Moon, as well as an atomic image of the sample’s crystal structure and a representation of the chemical signature of trivalent titanium. August Davis

 

Implications of Trivalent Titanium

In ilmenite, an atom of titanium typically loses four electrons when bonding with oxygen, resulting in a positive charge of 4+, known as the atom’s . From the sample we studied, a rock collected during the , we found that some of the in ilmenite actually has a charge of only 3+, referred to as trivalent titanium. Our measurement of trivalent titanium confirms what geologists had long suspected: that some titanium in lunar ilmenite exists in a lower charge state.

Trivalent titanium occurs only when is low. Thus, the abundance of trivalent titanium in ilmenite could tell us about the relative availability of oxygen in the Moon’s interior when the rock formed, around 3.8 billion years ago.

A Link to the Moon’s Early Chemistry

Our team has closely studied only one Moon rock so far, but from published studies we have identified more than 500 analyses of lunar ilmenite that could contain trivalent titanium. Studying these samples could reveal new details about how the Moon’s chemistry varies across different locations and time periods.

While our work highlights a link based on prior studies, the relationship between trivalent titanium in ilmenite and oxygen availability has not yet been quantified with targeted experimental data.

By conducting experiments that explore that link, ilmenite could reveal more details about the Moon’s interior. We also expect this relationship to apply to other planets and asteroids that don’t contain much chemically available oxygen, relative to Earth.

What’s Next?

These methods can be used to study many Moon rocks collected during the Apollo missions over 50 years ago, as well as future samples from upcoming , or rocks collected from the far side of the Moon, returned in 2024 by China’s .

One of plans to use their to explore how oxygen availability in magma affects the abundance of trivalent titanium in ilmenite. With experiments like this that build off our findings, we could potentially use ilmenite to reconstruct the history of ancient magmas from the Moon.

We believe future studies of lunar rocks using advanced scientific methods are essential for revealing the chemical conditions present on the ancient Moon. They could offer clues not only to its own history but also to the earliest chapters of Earth’s past – records that have since been erased from Earth.Image removed.

 

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